Hmm.
Earlier today, he instinctively released a Chromatic Orb spell whilst fighting street thugs, but since he had not prepared one, nothing happened. And the reason it was instinctual to do so was because in past incarnations he has habitually prepared and cast that particular spell, in similar vein to how his fingers are supposed to (judging by the message on his tattoo) remember how to open his locked journal.
Visualization exercise: Imagine you have a spellbook before you. You open to a blank page. You have an entire apothecary catalog's worth of components neatly set out in jars, and you have all the inks that you could desire. You dip your pen into the prepared ink, you bring it to the page, and - what do you do?