Is it true that she's an evil sorceress and would plausibly deserve it if she's about to be tried and sentenced to death?
Man, society as Healthy-Orphan knew it did not run on this 'deserves' concept at all. The leading figure is literally called the Dread Emperor and rules from the largest planet visible in the sky above.
Healthy-Orphan didn't think about her role in existence very hard. She saw that she had magical powers and wasn't a nobility-owned wizard and figured "oh I must be a dark sorceress then" and went off and did that. Healthy-Orphan killed people who had things she wanted and whom Orphan expected to not just hand those things over. She did have a tendency to go more for gold owned by merchants or armor owned by adventurers, and then trade that for food owned by peasants, rather than going after the peasants directly. She never killed any children, nor any beaten-down fathers helping to juggle underfed toddlers, and doesn't seem to have thought of this as Morality so much as Orphan just not particularly wanting to do that. She once saw a strong young man in a village and told him that he was now following around her army and sleeping with her whenever she wanted, and it did not particularly occur to her or him that "asking for consent" was a thing a dark sorceress could do.
Orphan has never heard of any such thing as a person being 'tried'. If you transgress in a village, the elders get together and decide what to do with you. If you transgress in a town, the town's ruler put in place by the Baron would decide what to do with you. She was aware in a distant way that there were such things as written laws, but they were not for villagers and bandit queens, or beggars and city guards, more for merchants and nobles.
As Orphan saw the world, if she was defeated by a baron, she'd obviously die on the spot. It didn't particularly occur to her that a dark sorceress would be imprisoned or judged, or enslaved or sold, or for that matter offered forgiveness or a chance to work for the government. She knew there were magic-users who worked for the government and nobles with powers, but they were not labeled as present or former dark-sorceress-bandit-queens, so they did not seem to have roles or fates commensurate with Orphan's.
Has this world heard of isekai before and would anybody believe her if she explained that she's not the real evil sorceress? Opalyn does not have a lot of hope about this one, probably all the evil sorceresses are always claiming "It wasn't me, that was someone else who set all those people on fire" but most of them are lying about it.
Orphan will not have reliably heard of most things her world has heard of. Orphan is from an illiterate peasant village. She forced a guy to teach her to sound out letters, so she could read stolen books about magic; but then there were also numbers in the magic books, and nobody around her knew how to do anything with numbers besides counting small quantities of coin, so Orphan gave up there.
None of the songs and tales coming to Opalyn Miller's stolen memory have anything about people from another world in there.
Who is in charge around here? What are they currently trying to do? How are they stuck? Does Opalyn have any way of helping them out in exchange for... whatever Opalyn ends up needing?
The Dread Emperor rules all, and none rule him. Orphan moved around a bit but never got outside the territory of Duke Greendeath.
Orphan does not have a concept that governments try to change or improve the way that things are, or that Eldrida (all the planets ruled by the Dread Emperor, Orphan does not seem to know very much about astronomy besides all that stuff staying up in the sky somehow) had been going anywhere it could get stuck on.
The village had spinning wheels, and a water-wheel turned by the river, and a crudely charmed ice-pit to keep food from spoilage which all the villagers chant over every 37 days. If there is such a thing as electricity it is not known to Orphan's memories.