The Tau are naturally very insensetive to Warp, and lack psykers in their own ranks. (They do have some Gue'vesa ones, but not enough for widespread training and experimentation.) However, they do possess somewhat advanced technology that is fueled, for once, by actual, living, healthy science and engineering that are completely understood by their practitioners. Their method of FTL travel is comparatively slow, but safe, and requires no witchcraft of any sort. Their technological prowess grows every passing year.
In general, they use a lot of automation. Having no readily avialable separate solution for FTL messaging, they use automated messenger ships. Much of their labor is automated, because exhaustion is contrary to the Greater Good, and efficiency is conductive to it. Much of their military consists of drones, because they, like the Eldar, do actually want to minimize causalities among their forces, but unlike the Eldar, who contuine to personally fight in melee because the Eldar, Tau take the obvious and reasonable approaches to it. Nearly exclusive use of long-range combat and heavy emphasis on combined arms and psychological warfare also greatly reduce the causalities.
The Tau Empire actively trades with nearby friendly worlds for goods, mercenaeries, services and technology, and when those worlds - such as the worlds of the Kroot - staunchly refuse to be welcomed into the fold, they refrain from their forceful annexation in an attempt to build up general goodwill.
And though they remain relatively small, inexperienced, and weak, they readily annex the worlds that are willing, or the worlds that are hostile (whose rank and file population generally, but not always, is willing to be annexed) and with each new planet that joins, they gain more resources, more technology, more understanding of the world, and more kinds of citizens with their own strengths.
They adapt, decide, and improve much faster than any other faction, needing months where other need decades despite their slow travel times. They have, for their relative naivete, the best epistemology, the most sober and pragmatic view of reality. They welcome and offer alliances and help rather than refuse them out of pride. They are ready to make sacrifices, but always think and weigh options and payoffs carefully before doing so. And unlike most others, who are trying to survive or fight, the Tau are trying to win.
And that is why the Tau Empire was the likeliest candidate to win.