There are other signs, in her story.
Esta's first domain ability from his Devil domain was "Hell's Corruption", a transient touch of evil upon a soul, like some vastly lesser form of Malediction, which makes a being "more susceptible to corruption" by bringing up its repressed desires.
It sounds a great deal more awesome than it actually is. In practice, you land a touch attack on an opponent, and then they'll be very mildly distracted by all their repressed desires welling up, for a number of moments equal to your cleric circle. So far as Esta knows, not a single paladin has ever fallen as a result of being so touched, in the history of Golarion and maybe of Creation.
They warn you, in seminary, if you have the rare Devil domain, that "Hell's Corruption" really really is not as useful as it sounds. At 4th circle they tell you the cautionary tale of a cleric with a beautiful but unresponsive mistress, whom he touched by Hell's Corruption to try to bring out her dark forbidden desires. And then it turned out her dark repressed desire was for LOTS OF BABIES obtained by any means necessary, and she was chosen by Pharasma as a cleric. And -- although the fact is not at all popularized in Cheliax -- Asmodeus and His Church do acknowledge that Asmodeus is in a chain of command with Pharasma, who is mightier than He even if She is so indifferent as to be useless as a tyrant. The point being, you don't Maledict Pharasmin clerics, or torture them, or even keep them as slaves -- although, again, that fact is not popularized. You just exile them out of Cheliax, unless they promise to be Lawful or maybe Evil and work with the Church. So the cleric lost his mistress, because her dark forbidden desire turned out to be not as gloriously Evil as he'd hoped.
Esta did, at one point, lay Hell's Corruption on Mariona, in the desperate hope that there would be anything hiding there to drive Mariona higher in Asmodeus's ranks.
Was Mariona's dark repressed desire to rule the world? To rule the Church, as Most High? To rise above Esta and crush him underfoot, beginning a game that Esta would have felt gratified to play, if only Mariona would play it?
No. Mariona's terrible dark repressed desire was for more medical emergencies to happen around her that she could treat by non-magical medicine, without just throwing a Cure spell at it.
After which Mariona began withholding Cure spells from her troops who'd injured themselves in stupid ways, and treating them nonmagically instead.
This is more or less exactly the sort of thing that seminary warned young Esta would probably happen, if he ever hoped for Hell's Corruption to do anything useful. It's shaped around being not literally utterly completely useless in combat; meaning it doesn't so much unearth the dark desire that is so tempting as to turn a paladin away from Good, as the dark desire that manages to be very distracting if your mind starts fantasizing about it.
But for Esta to now hear that 'Merrin' was supposedly running around all day long being a 7th-circle-grade non-magical field medic... has a certain familiar ring to it, is the point, here.