Tanya has only Sinnah's word for what Mind Purge does (in fact she doesn't have even that yet) or for who she could be in cahoots with here in her city, or that the language spell Tanya would be using to talk to those people is working correctly and cannot, for example, modify some things Tanya says and hears if Sinnah wants it to.
Some degree of trust is required to function in society. Sinnah could poisoned her through entirely nonmagical means; if a spell can induce 'empathy' then so can a chemical. It is not rational to respond to Sinnah mentioning a novel danger by suspecting her of being that danger. But how should Tanya calibrate her level of trust towards strangers in a completely new world with unknown dangers and unfamiliar social structures?
Tanya can't read minds, she can only talk to people. If she flies around quickly and asks a lot of random people in different cities and they all agree on something, without giving them a way to coordinate, they might be mistaken but they won't be lying. But would random people really know about what spells can do? Would she trust an informal poll subject to church propaganda about the abilities of 'empathy magic' over the word of a professional magic researcher? Not if she had any trust in the expert, which is rather the problem here! Sinnah might have biases and misconceptions about the local church, but random strangers aren't going to be any better. Tanya could... go back to that Baron, she supposes, or find the local equivalent, but if the authorities were going to tell strangers 'don't trust Sinnah, she enchants people' then they'd have arrested her already!
"I have no specific reason to mistrust you, or to trust any particular person's word over yours. Including about what Mind Purge does, or that that's what I'm buying. So I am going to trust you," because a society where a respected (?) person whom she met at random (??) immediately plots to enslave Tanya with an 'altruism spell' is not a society where she can function regardless.
"Of course physical effects affect the mind! This 'altruism magic' and the other things you mentioned are a novel attack vector for me, and I need to learn how to defend against them. The danger is my mind being subverted, not whether the means is a spell. Categorical defense or immunity is rarely possible, against any attack, but there must be defense strategies that make successful attacks rare? If I have to make it a rule not to let any unfamiliar magic target me I won't be able to go out in public!"